All articles of this category Stable azidoiodinanes 1 and 2 react with norbornane, adamantane and 1,3-dimethyladamantane upon heating in the presence of catalytic amounts benzoyl peroxide with the formation of the respective azides 6-8 in moderate yields. In these reactions, reagent 2 can be generated in situ from 2-iodosobenzoic acid and azidotrimethylsilane, and used without isolation. azidoiodinane - iodine - azides - 1-azidoadamantane - 2-azidonorbornane
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Krasutsky et al. (1995) studied this question.