Two faces: Semifluorinated Janus-dendritic benzamides self-assemble into supramolecular bilayered pyramidal columns with diameters over twofold greater than those of columns generated from twin-dendritic benzamides (see model). The Janus-dendritic benzamides are synthesized by selectively replacing the aliphatic chains from the periphery of one of the two dendrons of a twin-dendritic benzamide with semifluorinated chains.
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Percec et al. (2005) studied this question.
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