A novel polyaniline (PANI)/H2Ti4O9 lamellar nanocomposite has been synthesized by in situ polymerization using aniline intercalation compound (ANI)/H2Ti4O9 as the intermediate. According to the experimental results, the ANI within the interlayer spacing of the layered H2Ti4O9 material may be oriented in a single-layer arrangement, with the benzene rings perpendicular to the layer sheets. After polymerization, a monolayer of PANI chains within the confined galleries was produced. The PANI/H2Ti4O9 nanocomposite has been studied by electrochemical methods, which revealed good redox activity.
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Liu et al. (2010) studied this question.
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