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In crystals with two short axes it is easy to partition free volume into local components by plotting a profile of the free areas of planes parallel to the plane defined by the short axes. Local free volume is used to analyze radical motion in bis-undecanoyl peroxide. It is relevant to melting-point alternation in long-chain compounds and to packing in a lipid bilayer.
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J. Michael McBride (1983) studied this question.
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