The ternary nitridochromate Ce 2 [CrN 3 ] (orthorhombic Immm , a = 378.56(1) pm, b = 340.88(2) pm, c = 1251.27(4) pm) was synthesized in single phase form from the binary nitrides utilizing the decomposition of CrN to Cr 2 N. Magnetic susceptibility measurements as well as X‐ray absorption spectroscopy indicate a Ce 4+ (4 f 0 ) electronic state and in turn an oxidation state of +1 for chromium provided –3 for nitrogen.
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Bräunling et al. (2011) studied this question.
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