Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]+ and [Fe(bpmb)(CN)2]− building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb=1,2-bis(pyridine-2-carboxamido)-4-methylbenzene.
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Ni et al. (2005) studied this question.
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