The first use of triethylene glycol (H(2)teg) in Fe/Ln chemistry affords two series of tetranuclear {Fe(III)(2)Ln(III)(2)} coordination clusters possessing defect-dicubane cores. A change in the synthetic procedure results in a different arrangement of the relative positions of the 3d and 4f elements offering a means to steer the structural and electronic features within a 3d-4f system.
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Peng et al. (2012) studied this question.
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