On the rack: Splitting of the peripheral metal-based oxidation, which indicates a large coupling between the redox sites, has been obtained in polymetallic arrays composed of rack-type complexes containing two, three, four, or six RuII subunits appended to hydrazone-based molecular strands (see picture). The relatively small coupling attenuation parameter calculated for the metal-based, cationic subunit(s) suggests molecular-wire behavior.
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Loiseau et al. (2007) studied this question.
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