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Formation, optical properties and structures of bis( o ‐hydroxybenzylideneamine)copper(II) chelates of poly( L ‐lysine), poly( L ‐ornithine), and poly( L ‐α,β‐diaminobutyric acid) were investigated. Experimental evidence was obtained for a definite structure of these polycomplexes in alcoholic/aqueous solution. Structural features showed that asymmetric polypeptide matrices bind metal chelates stereospecifically. On the basis of these results stereoselective reactions on bis( o ‐hydroxybenzylideneamine)copper(II) polycomplexes are expected.
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Dentini et al. (1974) studied this question.
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