The MnIVO unit in the five-coordinate oxo(porphyrinato)manganese(IV) complex 2, which is formed by oxidation of the bromo(porphyrinato)manganese(III) complex 1 with potassium peroxycarbonate, was characterized by X-ray absorption spectroscopy. The relatively long MnO bond (1.69±0.03 Å) is probably attributable to the high-spin state and the low polarizability of the half-filled t subshell of high-spin MnIV.
No takes yet. Share an insight, caveat, or question.
Charnock et al. (1995) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: