Square-planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons.
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Knof et al. (1993) studied this question.
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