Tricarbonyl(2,6-disubstituted-1-bromobenzene)chromium was treated with ortho-substituted phenylboronic acids in the presence of a palladium(0) catalyst to give mono-Cr(CO)3 complexes of biphenyl componds with a complementary axial chirality depending upon the nature of ortho-substituent of the phenylboronic acids
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Uemura et al. (1994) studied this question.
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