A hydroxyapatite-supported Pd nanocluster (PdHAP) efficiently catalysed the dehalogenation of various organic halides in the presence of atmospheric molecular hydrogen; chlorobenzene gave benzene in an excellent TON of 10 000 for 10 h. Moreover, the dehalogenation of halophenols in aqueous conditions was also achieved.
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Hara et al. (2004) studied this question.
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