Totally rad: Synthetic methods have been developed for the formation of Csp3F bonds by reaction of C-centered radicals with fluorine sources. Three complementary strategies, which differ in the mode of generation of the alkyl radical intermediate, are described. These include olefin hydrofluorination, decarboxylative fluorination, and aliphatic CH fluorination.
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Sibi et al. (2013) studied this question.
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