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January 1, 1971Journal of the Chemical Society A Inorganic Physical Theoretical

Zerovalent platinum chemistry. Part VI. The reactions of bis- and tris-triphenylphosphineplatinum(0) with hydrogen sulphide, hydrogen selenide, sulphur, and related molecules

Renato Ugo G. La Monica Sergio Cenini Augusto Segre F. Conti

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Abstract

The reactions of Pt(PPh3)n(n= 2 or 3) with H2M, HMPh, and M (M = S or Se) to form adducts have been studied. The reactivity of the products towards soft and hard reagents has been investigated and compared with that of related H2M, HMPh, and M adducts of some RhI and IrI triphenylphosphine complexes. The results agree with the proposed mechanisms of poisoning of metal surfaces by species such as H2M or M.

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Ugo et al. (1971) studied this question.

synapsesocial.com/papers/6a86ba27c27ad527967cb24a https://doi.org/10.1039/j19710000522

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