Materials synthesis study demonstrates the mechanochemical preparation of ternary potassium transition metal chlorides, indicating a versatile solvent-free route for complex halide synthesis.
Ternary halide systems KM II Cl 3 (M II = Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn) have been prepared by mechanochemical synthesis. Furthermore, TiCl 2 was converted to Ti 7 Cl 16 by mechanochemical treatment. For most samples, the X‐ray powder diffraction patterns could either be assigned to isotypic structures or were found in accordance with reference data. The monochloride systems of Ti, Co and Zn were extended to their double chloride stoichiometry K 2 M II Cl 4 .
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Pawelke et al. (2009) studied this question.
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