The chromium doped spinel crystals, MgAl2O4:Cr3+, have been grown using floating zone technique and its application for the fiber-optic thermometer is discussed on the basis of the temperature dependence of the fluorescence lifetime. Lifetimes of the spinel crystals (τ=10 ms), which decrease with temperature, were about 3 times larger than that of the ruby crystals (τ=4 ms) at room temperature. Temperature coefficients of the photoluminescence (PL) lifetimes for spinel crystals (37 μs/K) are also 3 times longer than that for the ruby crystals (10 μs/K). The spinel crystals are potentially useful sensor probes for the fiber-optic thermometer, which have an advantage of high sensitivity due to long PL lifetime and large temperature coefficient.
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Aizawa et al. (2002) studied this question.
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