Chiral tridentate ligand: A chiral diene–rhodium complex (1; see scheme) was found to catalyze the intermolecular asymmetric cyclopropanation of alkenes with dimethyl diazomalonate to give 1,1-cyclopropane diesters in good yields and with high enantioselectivity.
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Nishimura et al. (2010) studied this question.
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