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An operationally simple protocol to access 2,2‐chlorofluoro‐, and 2,2‐bromofluorobicyclopentanes (BCPs) via commercially available, inexpensive, non‐ozone depleting, and bench stable reagents is reported. The resulting BCP products are tolerated in diverse, synthetically relevant post‐functionalization reactions. Gram‐scale reactions to prepare the BCPs are also included.
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Zhu et al. (2025) studied this question.
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