The deviation of the temperature dependence of the magnetocrystalline anisotropy in a K0.4[Cr(CN)6][Mn(S)-pn](S)-pnH0.6 uniaxial ferrimagnetic molecular magnet from the theoretical predictions for this dependence are revealed and discussed. The Dzyaloshinskii–Moriya interaction, which becomes significant at low temperatures and causes non-collinear ordering of spins, is shown to be the source of this deviation.
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Кирман et al. (2019) studied this question.
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