The thermal conductivity of H 2 -N 2 and H 2 -CO 2 mixtures has been measured from -15 to 200°C by using the thick-wire variant of the hot-wire method. The experimental values have been compared with those calculated from the Hirschfelder-Eucken formula. Although fairly satisfactory agreement between theory and experiment is obtained it appears that for a precise interpretation of the thermal conductivity of polyatomic gas mixtures a better representation of the cross-relaxation phenomena is necessary.
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Mukhopadhyay et al. (1967) studied this question.
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