REARRANGEMENT OF ACETYLENIC COMPOUNDS WITH PARTICIPATION OF THE π-ELECTRONS OF THE TRIPLE BOND

CONTENTS I. Introduction 670 II. Prototropic rearrangement of acetylenic hydrocarbons 670 III. Anionotropic rearrangement of acetylenic alcohols 671 IV. Acetylene–allene rearrangement 675 V. Acetylene–allene–cumulene rearrangement 678 VI. Rearrangement of acetoacetates and of acetates of acetylenic alcohols 679 VII. Rearrangement of acetylenic compounds containing other functional groups 679