All articles of this category Application of the molybdenum catalysed hydrostannation towards propargylic esters of amino acids allows for the regioselective synthesis of α-stannylated allylic esters, suitable substrates for chelate Claisen rearrangements. α-Stannylated allylic carbonates can be subjected to palladium catalysed allylic alkylations using chelated amino acid ester enolates as nucleophiles. The stannylated amino acids obtained can be further modified via cross-coupling reactions. allylic alkylation - Claisen rearrangement - cross coupling - hydrostannation - molybdenum
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Kazmaier et al. (2000) studied this question.