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January 1, 2002Chirality

Overall view of the use of chiral platinum(II) complexes as chiral derivatizing agents (CDAs) for the enantiodiscrimination of unsaturated compounds by ¹⁹⁵Pt NMR

Gloria Uccello‐Barretta Raffaella Bernardini Federica Balzano Piero Salvadori

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Abstract

The use of organometallic CDAs based on ethene‐platinum(II) complexes, covalent cis‐ and trans‐ dichloro(Am)(ethylene)platinum(II), and ionic [PtCl 3 (C 2 H 4 )] − [AmH] + , containing primary and secondary amines, for the 195 Pt NMR enantiodiscrimination of chiral unsaturated compounds is reviewed. Chirality 14:484–489, 2002.

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Uccello‐Barretta et al. (2002) studied this question.

synapsesocial.com/papers/6a86f678e925a1267eca0264 https://doi.org/10.1002/chir.10073

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1NMR determination of enantiomeric purityOriginal Research · 1991 · 875 citations
2Determination of enantiomeric purity using chiral lanthanide shift reagentsOriginal Research · 1974 · 241 citations
3Direct Determination of the Enantiomeric Purity of Chiral Trisubstituted Allenes by Using Permethylated Cyclodextrin as a Chiral Solvating AgentOriginal Research · 1994 · 39 citations
4Simple organometallic chiral derivatising agents for the <sup>31</sup> P n.m.r. assay of the enantiomeric purity of certain η <sup>2</sup> -donorsOriginal Research · 1987 · 17 citations
5Determination of the enantiomeric purity of chiral allyl alcohols and allyl ethers by platinum-195 NMR spectroscopyOriginal Research · 1988 · 19 citations

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