Wilkinson‐type rhodium hydrogenation catalysts immobilized on oxidic supports via mono‐ and bidentate phosphine linkers have been studied by 31 P solid‐state NMR, and their recycling stability and lifetime with respect to hydrogenation of 1‐dodecene, 2‐cyclohexen‐1‐one, and 4‐bromostyrene have been improved substantially.
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Merckle et al. (2003) studied this question.
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