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The performance of a set of mono- and bimetallic Rh( i ) and Ir( i ) complexes bearing carbene-linker-carbene (CXC) bis-triazolylidene ligands (with X = O, N) coordinated in a bridging or chelating fashion was evaluated in the hydrothiolation of alkynes.
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Tolley et al. (2020) studied this question.
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