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Laves phase compounds Zr(Fe, Co) 2 have MgCu 2 structure and Zr(Fe, Mn) 2 change the structure from MgCu 2 type to MgZn 2 type with composition change. Both compounds change from ferromagnetism to paramagnetism with decreasing Fe content and the magnetic moment of Fe, Mn, Co decrease from 1.62, 0.62, 0.62 µ B to zero. This decrease is caused by a change of the local symmetry of the nearest neighbors in Zr(Fe, Mn) 2 and by a change of the configuration in Zr(Fe, Co) 2 . An effect of configuration for the magnetic moments in Zr(Fe, Co) 2 is evaluated and compared with the hyperfine fields of Fe reported by Swartzendruber and Bennet.
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K. Kanematsu (1971) studied this question.
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