We report the first Raman measurements on a matrix sample prepared by the mass-selected ion deposition technique. Vanadium dimer ions, produced by sputtering, were mass selected with a Wien filter and codeposited with Ar and electrons. Raman spectra gave ωe″= 536.9(1.1) and ωexe″ = 4.1(0.1) cm−1, in good agreement with previous measurements.
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Hu et al. (1991) studied this question.
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