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Highly fluorescent main-chain-type organoboron quinolate polymers were prepared by means of Sonogashira−Hagihara coupling reaction between diyne monomers and methyl-substituted diiodo-organoboron quinolates. By combining methyl substitution of quinolinol ligands and incorporation of organoboron quinolate into polymer main chain, more efficiently luminescent materials with blue-shifted emission were successfully synthesized.
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Nagata et al. (2008) studied this question.
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