We have observed KrO excimer emission resulting from photoexcitation of cryodeposited films of Kr:N₂O. Both direct and exciton-enhanced dissociation of O(¹S) from N₂O was observed. Our data yield a direct threshold of 7.9 eV and a relative quantum yield at higher resolution than recently reported for the gas phase. The large luminescent intensity observed indicates excimer decay via allowed ¹Σ⁺→¹Π and ¹Σ⁺→¹Σ⁺ transitions.
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Monahan et al. (1977) studied this question.
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