Single crystals of α-Methyl-D-glucopyranoside x irradiated at 77 K contain five free radical species observed by ESR and ENDOR spectroscopy. Four of these have been assigned molecular loci: a primary alkoxy radical at O6, a secondary alkoxy radical at O2, a deprotonated hydroxyalkyl radical at C6, and a radical due to hydrogen abstraction at C5. Structural considerations and mechanisms of formation are discussed.
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Madden et al. (1979) studied this question.
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