All articles of this category Dichloro[(2-dimethylamino)propyldiphenylphosphine]palladium (PdCl 2 (alaphos)) and dichloro[1,3-bis(diphenylphosphino)-propane]palladium (PdCl 2 (dppp)) were found to be much more effective catalysts than PdCl 2 (PPh 3 ) 2 and other palladium complexes for cross-coupling of sterically congested aryl triflates with aryl and alkynyl Grignard reagents. cross-coupling - Grignard reagent - aryl triflate - palladium catalyst
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Kamikawa et al. (1997) studied this question.
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