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April 17, 1998Inorganic Chemistry

Spectroelectrochemical Analysis of the Intervalence Band in Mixed-Valence Di- and Tetranuclear Ru Complexes by the Flow-Through Method

Masa‐aki Haga Md. Meser Ali Hiroyasu Sato Hideaki Monjushiro Koichi Nozaki Kenji Kano

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Abstract

New convenient spectral analysis of IT band for partially oxidized species was developed by using the combination of digital simulation analysis of a reversible CV curve and an electrochemical titration with flow-through electrolysis. This method can be applicable not only for dinuclear Ru complexes but also dendritic Ru tetranuclear complexes.

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Haga et al. (1998) studied this question.

synapsesocial.com/papers/6a871dbf3a1d8ec5fdd3df83 https://doi.org/10.1021/ic970794r

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