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A novel three-dimensional (3D) microporous lanthanide−organic framework [Nd(2,5-pydc)(Ac)(H 2 O)] n ·2 n H 2 O ( 1 ) has been prepared under hydrothermal conditions. The results of an X-ray crystallographic analysis revealed that compound 1 has a 3D nanotubular structure. From the topological point of view, the intricate 3D framework of compound 1 can be specified by the Schläfli symbol (4 2 6 3 8) as a zeolite ABW net. The H 2 adsorption isotherm at 77 K shows an uptake of 132 cm 3 g −1 at 1.0 atm.
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Huang et al. (2007) studied this question.
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