Experimental study demonstrates bulk enantiomeric excess in a chiral open-framework fluoroaluminophosphate, highlighting a new route to homochiral inorganic materials.
A novel chiral open-framework fluoroaluminophosphate [C4N3H16][Al6P3O12F6(OH)6] was hydrothermally synthesized using diethylenetriamine as a structure-directing agent. The significant enantiomeric excess of the bulk product was confirmed by the solid state vibrational circular dichroism (VCD) spectrum.
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Tong et al. (2013) studied this question.
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