Syn and anti conformational isomers of 3-furylchlorocarbene were characterized in low-temperature matrixes by IR, UV/vis, chemical trapping, and calculational modeling. Displaying significantly different electronic spectra, the two isomeric carbenes could be photochemically interconverted. At shorter wavelengths, the carbene rearranges to a conjugated methylenecyclopropene.
No takes yet. Share an insight, caveat, or question.
Khasanova et al. (1999) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: