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On treating with LDBB, 2-substituted 3-phenylthioalkyl silyl ethers were converted to the corresponding 3-silylated alkanols with high anti selectivity. Application to silyl ethers containing allylic sulfide moieties provided a useful methodology for the regio- and stereo-defined synthesis of allylsilanes.
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Marumoto et al. (1992) studied this question.
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