The study reports on the impact of inorganic fertilisers with or without farmyard manure on the cation exchange capacity (CEC), cationic balance and microbial biomass carbon (C), nitrogen (N) and phosphorus (P) in a savanna Alfisol after 45 years of cultivation. Soils for the study were fertilised with N or N+P+K, cow dung (D), D+N and D+N+P+K for 45 years. Inorganic fertiliser significantly reduced CEC, exchangeable cations and upset the cationic balance. The reduction in CEC and exchangeable cations seemed to operate via organic matter depletion and pH reduction. Similarly inorganic fertiliser stressed microbial activity evidenced by the low amounts of microbial biomass C, N and P compared to the soil under native vegetation and the soils fertilised with D+N and D+N+P+K. From the perspective of the flows of C, N and P through soil microbial biomass, and cation exchange properties and prevention of nutritional imbalances involving basic cations, a rational fertilisation program for savanna Alfisols is one that combines inorganic fertilisers with farmyard manures.
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Goladi et al. (1997) studied this question.