An ionic liquid, 1-ethyl-3-methylimidazolium bromide, is used as reaction medium for the synthesis and crystallization of a coordination polymer, (EMI)[Cd(BTC)] ( 1 ) (EMI = 1-ethyl-3-methylimidazolium, BTC = 1,3,5-benzenetricarboxylate), which forms an anionic three-dimensional framework with 1-ethyl-3-methylimidazolium cations located in the void space.
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Liao et al. (2006) studied this question.
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