Mesh‐Shaped Nanopatterning of Pt Counter Electrodes for Dye‐Sensitized Solar Cells with Enhanced Light Harvesting

A facile process to produce large‐area platinum (Pt) counter electrode platforms with well‐arrayed, mesh‐shaped nanopatterns using commercially available TiO 2 paste and poly(dimethyl siloxane) (PDMS) nanostamps is presented. The process involves mesh‐shaped (200 nm × 200 nm) nanopatterning of a TiO 2 scaffold onto a fluorine‐doped tin oxide (FTO) substrate, followed by Pt sputtering. The structure and morphology of the counter electrodes are characterized by a field emission scanning electron microscope (FE‐SEM) and an atomic force microscope (AFM). Solid‐state dye‐sensitized solar cells (ssDSSCs) fabricated with these mesh‐shaped Pt counter electrodes showed an efficiency of 7.0%. This is one of the highest efficiencies observed for N719 dye and is much higher than that of devices with non‐patterned, thermally deposited electrodes (5.4%) or non‐patterned, sputtering deposited electrodes (5.7%). This improvement is attributed to enhanced light harvesting and a greater surface area and has been confirmed by incident photon‐to current efficiency (IPCE), electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV) measurements.