The various methods of obtaining the limiting laws of strong electrolytes are briefly discussed. It is shown that the dependence of these limiting laws on the temperature, the dielectric constant of the solvent and the volume of the solution can be deduced from the Gibbs-Helmholtz equation and the virial theorem of Clausius. The Debye-Hückel and the Kramers limiting laws are found to be of the same type as these general limiting laws, with numerical coefficients obtained thanks to the use of the Poisson equation.
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Pierre Van Rysselberghe (1933) studied this question.
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