The anionic half-sandwich complexes L−(ROMe, OEt) act as tridentate ligands. They form inert complexes with metals in low oxidation states, an unusual behavior for oxygen ligands. For example, the Co2Rh2 complex [LRh(μ-CO)3RhL], ROEt, was prepared and its structure determined by X-ray analysis.
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Kläui et al. (1985) studied this question.
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