November 16, 2020Journal of the American Chemical SocietyOpen Access

Electronic Control of Spin-Crossover Properties in Four-Coordinate Bis(formazanate) Iron(II) Complexes

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Abstract

-substituent has a different influence depending on whether it is present at the C-Ar or N-Ar rings, which is ascribed to the opposing effect on metal-ligand σ- and π-bonding.

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Milocco et al. (2020) studied this question.

synapsesocial.com/papers/6a87a9aeca6eee08f4f3014f https://doi.org/10.1021/jacs.0c10010

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Abstract

-substituent has a different influence depending on whether it is present at the C-Ar or N-Ar rings, which is ascribed to the opposing effect on metal-ligand σ- and π-bonding.

Electronic Control of Spin-Crossover Properties in Four-Coordinate Bis(formazanate) Iron(II) Complexes

Abstract

Discussion

Cite This Study

Electronic Control of Spin-Crossover Properties in Four-Coordinate Bis(formazanate) Iron(II) Complexes

Abstract

Discussion

Cite This Study

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