Most currently used measures of inter‐rater agreement for the nominal case incorporate a correction for ‘chance agreement.’ The definition of chance agreement is not the same for all coefficients, however. Three chance‐corrected coefficients are Cohen's κ, Scott's Π, and the S index of Bennett, Goldstein and Alpert, which has reappeared in many guises. For all three measures, chance is defined to include independence between raters. Scott's Π involves a further assumption of homogeneous rater marginals under chance. For the S coefficient, uniform marginals for both raters under chance are assumed. Because of these disparate formulations, κ, Π, and S can lead to different conclusions about rater agreement. Consideration of the properties of these measures leads to the recommendation that a test of marginal homogeneity be conducted as a first step in the assessment of rater agreement. Rejection of the hypothesis of homogeneity is sufficient to conclude that agreement is poor. If the homogeneity hypothesis is retained, Π can be used as an index of agreement.
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Rebecca Zwick (1986) studied this question.
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