In the presence of HSiEt 3, the rhodium system formed by addition of PPh 3 to [Rh(μ-Cl)(COE) 2 ] 2 (COE = cyclooctene) simultaneously catalyzes the dehalogenation of polychloroarenes and the formation of Et 3 SiCl.
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Esteruelas et al. (1999) studied this question.
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