The control of the intracolumnar organization of disc-shaped polycyclic aromatic hydrocarbons has essential influence on material’s properties including thermotropic behavior and charge carrier transport which are crucial for applications in organic electronics. The utilization of a broad toolbox of peripheral substitution allows well-defined modification of the molecular interactions and packing within helical columnar stacks (see figure).
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Pisula et al. (2010) studied this question.
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