A new and efficient method for oxidising sulfides selectively to sulfoxides has been developed with atmospheric oxygen, in the presence of isobutyraldehyde and catalysed by NiII complexes such as bis[1,3-bis-(p-methoxyphenyl)-1,3-propanedionato]nickel, [Ni(dmp)2], and bis[acetylacetonato]nickel, [Ni(acac)2].
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Vincent et al. (1994) studied this question.
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