The kinetics of the gamma‐radiation induced free‐radical chain reaction in solutions of carbon tetrachloride in cyclohexane (RH) has been investigated in the temperature range of 303–383°K. Trichloromethyl radicals were produced by the reaction of radiolytically generated cyclohexyl radicals with carbon tetrachloride. The kinetics of the following reactions were investigated: equation image The following rate expression was obtained: The error limits are the standard deviation from the least mean square Arrhenius plots. Effects of phase on the kinetics of reactions (3) and (4) are considered.
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Katz et al. (1976) studied this question.
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