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How to describe the ``electric double layer'' that is at the root of all electrokinetic phenomena such as electrophoresis and electro-osmosis? A new theoretical approach, introducing the concept of a surface potential trap and applying the constraint of global charge neutrality rigorously, answers this century-old question in the context of contemporary electrokinetics involving nanoscale systems and time-dependent electric fields.
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Wan et al. (2014) studied this question.
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