A novel Tröger base derived cyclophane bearing mercaptoimidazole groups on the alkyl chains as blanches of 6H,12H-5,11-methanodibenzo-[b,f][1,5]diazocine skeleton was synthesized in order to investigate the ability as macrocyclic enzyme models to incorporate phosphotyrosine in future.The design and synthesis of macrocyclic ring systems play an important role in host-guest chemistry.1
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Miyake et al. (2002) studied this question.
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